Reactive
dividing wall column (RDWC) is the integration of reactive distillation
and dividing wall column, which simultaneously has the advantages
of both process intensification techniques. However, due to the strong
coupling and nonlinear characteristics, the research of RDWC is still
insufficient in terms of control and operation. Moreover, the energy-efficiency
and safety analysis of the process should be also considered when
studying the control configuration of RDWC. In this paper, the process
of producing n-butyl acetate in a reactive dividing
wall column is taken as a study case. On the basis of the controllability
index and exergy analysis method of steady-state process, the basic
control structure with robust stability and energy-efficiency is selected.
Five proportional-integral (PI) control schemes are further established
on the preferred basic control configuration. Integral absolute error
(IAE) and process route index (PRI) are applied as evaluation criteria
to test the operability and hazard of the system in dynamic simulation,
respectively. The results show that the CS1 control structure has
the best stability compared with other control schemes, but its safety
performance is the worst. The CS4 control structure combines controllability,
energy-efficiency, and safety through a comprehensive analysis, which
can be used as the preferred control scheme.