Abstract:Three binuclear species [LCo III 2 (μ-Pz) 2 ](ClO 4 ) 3 (1), [LNi II 2 (CH 3 OH) 2 Cl 2 ]ClO 4 (2), and [LZn II 2 Cl 2 ]PF 6(3) supported by the deprotonated form of the ligand 2,6-bis[bis(2pyridylmethyl) amino-methyl]-4-methylphenol were synthesized, structurally characterized as solids and in solution, and had their electrochemical and spectroscopic behavior established. Species 1-3 had their water reduction ability studied aiming to interrogate the possible cooperative catalytic activity between two neighbo… Show more
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