The
use of fluorescence slices and other regular methods tend to
be limited in resolution as a result of optical microscopy issues
when they are applied to characterize oil occurrences in tight sand
micro/nanopores. To address this, an experimental method that combines
the use of environmental scanning electron microscopy (ESEM) and energy-dispersive
spectrometry (EDS) is proposed in this paper on the basis of a large
number of experiments; oil was observed during these tests using ESEM,
and the carbon (C) content was qualitatively evaluated using EDS.
Data show that the most appropriate experimental parameters were a
sample room pressure of 10 Pa, a working distance of 5 mm, a working
voltage of 15 kV, and an electronic beam spot size of 4.5 nm. The
experimental analysis of six samples from five wells within the Songliao
and Sichuan Basins, China, reveals that oil mainly occurs in the form
of oil films and oil droplets within micro-intergranular seams, micro/nano-intergranular
pores, and nano-intragranular pores. Observations aslo show that oil
films are found mainly within micro-intergranular seams and micro-intergranular
pores, while oil droplets, in contrast, are mainly found within nano-intragranular
pores. Data show that the occurrence space occupied by oil films is
relatively larger, having planar dimensions between 200 nm and 10
μm by between 1 and 10 μm. The oil films adhere to the
pores just like bonding with the pores. The content of the C element
in the oil films is 50–90%. In contrast, the occurrence space
occupied by oil droplets is relatively smaller, with intragranular
pore plane dimensions predominantly between 200 and 1000 nm by between
200 and 1000 nm. Data also show that oil droplets are controlled by
the shape of intragranular pores and occur at scales between 200 and
1000 nm by between 200 and 1000 nm. Thus, although the occurrence
space occupied by oil droplets is smaller than that of oil films,
the development of numerous intragranular dissolved pores provides
the necessary room for oil droplets to occur. The EDS data of these
droplets show that the content of the C element of the oil droplets
in intragranular pores is relatively small, mainly concentrated between
15 and 30%.