2009
DOI: 10.1007/s10646-009-0380-8
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Distribution of butyltins (TBT, DBT, MBT) in sediments of Gulf of Cádiz (Spain) and its bioaccumulation in the clam Ruditapes philippinarum

Abstract: Surface sediment samples were analyzed for organotins namely tributyltin (TBT), dibutyltin and monobutyltin from six areas located in the Gulf of Cádiz (14 stations), Spain. The total butyltin ranged between undetected and 1,580 ng Sn g(-1). TBT generally prevailed in most of the samples, suggesting fresh inputs of butyltin compounds and/or less degradation of TBT. The observed levels of butyltins at several sites are much higher than that required to induce toxic effect on marine organisms, suggesting that th… Show more

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Cited by 20 publications
(4 citation statements)
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“…In general, low concentrations of BTs detected in surface sediments may be a result of (i) sampling location, as some samples may be located far from the main sources, (ii) a decrease in input because of the TBT-based antifouling paint ban, and (iii) degradation in the environment caused by hydrodynamic processes and human activities, such as dredging and ship traffic (Radke et al 2008). Whereas in some environments, TBT impact was reduced after the antifouling ban (Airaksien et al 2010;Garg et al 2009), in other areas (mainly development countries), the concentrations detected after the ban were higher (Filipkowska et al 2011;Kim et al 2011;Kim et al 2015). Corresponding with these results, Paranaguá and Itajaí (located along the Brazilian southern coast) were the most impacted estuaries, as the presence of BTs was observed in biotic and abiotic matrices.…”
Section: Integrative Resultsmentioning
confidence: 62%
“…In general, low concentrations of BTs detected in surface sediments may be a result of (i) sampling location, as some samples may be located far from the main sources, (ii) a decrease in input because of the TBT-based antifouling paint ban, and (iii) degradation in the environment caused by hydrodynamic processes and human activities, such as dredging and ship traffic (Radke et al 2008). Whereas in some environments, TBT impact was reduced after the antifouling ban (Airaksien et al 2010;Garg et al 2009), in other areas (mainly development countries), the concentrations detected after the ban were higher (Filipkowska et al 2011;Kim et al 2011;Kim et al 2015). Corresponding with these results, Paranaguá and Itajaí (located along the Brazilian southern coast) were the most impacted estuaries, as the presence of BTs was observed in biotic and abiotic matrices.…”
Section: Integrative Resultsmentioning
confidence: 62%
“…High TBT concentrations in relation to the sum total of DBT and MBT (butyltin degradation index; BDI < 1) in the samples indicate the recent input of TBT into the environment. 63 In the current study, the BDI ranged from 0.3 to 4.6 (Table 1), and the highest BDI was observed in sediments collected along the Swedish coast. The calculated BDI in sediments collected from stations KM, UW, and 20 located along the Polish coast was a little larger than 1, which indicated no recent inputs of TBT into the environment.…”
Section: Alkylphenols Alkylphenol Ethoxylates and Bisphenol Amentioning
confidence: 49%
“…The quantitative importance of TBT degradation can be evaluated following a TBT degradation index. Butyltin degradation index (BDI) ( BDI <1 indicates recent input of TBT [14]. In the TGRR, the BDI calculated ranged from <0.01 to 2.21 in the surface water ( Table 2).…”
Section: Resultsmentioning
confidence: 99%