Rod. dos Tamoios, km 5,5, 12228-001 São José dos Campos -SP, BrasilRecebido em 21/10/08; aceito em 4/5/09; publicado na web em 1/10/09 TEMPERATURE MEASUREMENTS BY OH LIF AND CHEMILUMINESCENCE KINETIC MODELING FOR ETHANOL FLAMES. OH LIF-thermometry was applied to premixed ethanol flames at atmospheric pressure in a burner for three flame conditions. Flame temperatures were simulated from energy equation with PREMIX code of CHEMKIN software package for comparison. A kinetic modeling based on a model validated through chemiluminescence measurements and on a set of reactions for nitrogen chemistry was evaluated. Marinov's mechanism was also tested. Sensitivity analysis was performed for fuel-rich flame condition with F = 1.34. Simulated temperatures from both reaction mechanisms evaluated were higher than experimental values. However, the proposed kinetic modeling resulted in temperature profiles qualitatively very close to the experimental.