2018
DOI: 10.26434/chemrxiv.6686585
|View full text |Cite
Preprint
|
Sign up to set email alerts
|

Divergent Reactivity of CO2 and CO and Related Substrates at the Nickel Carbon Double Bond of (PCcarbeneP)Ni(II) Pincer Complexes

Abstract: The addition of carbon monoxide (CO), carbon dioxide (CO<sub>2</sub>) and isoelectronic isocyanide and isocyanates to the nickel carbene bond in PC<sub>carbene</sub>P pincer complexes is reported. For CO and CNR, irreversible group transfer reactions are observed, while for CO<sub>2</sub>, a reversible 2+2 addition to the carbene moiety occurs. The course of the CO and CO<sub>2</sub> reactions are strongly affected by the nature of the PC<sub>carbene</su… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 46 publications
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?