2021
DOI: 10.1002/ange.202100443
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Diversifying Metal–Ligand Cooperative Catalysis in Semi‐Synthetic [Mn]‐Hydrogenases

Abstract: The reconstitution of [Mn]-hydrogenases using as eries of Mn I complexes is described. These complexes are designed to have an internal base or pro-base that may participate in metal-ligand cooperative catalysis or have no internal base or pro-base.Only Mn I complexes with an internal base or pro-base are active for H 2 activation;o nly [Mn]hydrogenases incorporating such complexes are active for hydrogenase reactions.These results confirm the essential role of metal-ligand cooperation for H 2 activation by th… Show more

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