1999
DOI: 10.1006/jcis.1999.6195
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Dodecyl Pyridinium/Alkali Metals Ion Exchange on Muscovite Mica

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Cited by 20 publications
(26 citation statements)
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“…The MB + /K + exchange was actually fast at the beginning and half of the surface ions were exchanged within 1 h, then the exchange slowed down and took several days to reach the saturation value. This is a phenomenon which was also observed and discussed in case of the dodecylpyridinium ion (NDP + )/K + exchange (31). It is also noteworthy that the amounts of adsorbed MB + and released K + are in good agreement within the experimental error.…”
Section: Resultssupporting
confidence: 53%
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“…The MB + /K + exchange was actually fast at the beginning and half of the surface ions were exchanged within 1 h, then the exchange slowed down and took several days to reach the saturation value. This is a phenomenon which was also observed and discussed in case of the dodecylpyridinium ion (NDP + )/K + exchange (31). It is also noteworthy that the amounts of adsorbed MB + and released K + are in good agreement within the experimental error.…”
Section: Resultssupporting
confidence: 53%
“…To overcome this problem the surface of naturally weathered mica is usually saturated with an index cation, which is laborious and should be carefully monitored, before the measurement of its CEC (12). The exchange rate of these cations depends on their relative affinities to mica (6,31). In order to make a reasonable comparison between the different methods of CEC measurement, the surface of the mica used has to be saturated with a cation which has high affinity to it.…”
Section: Resultsmentioning
confidence: 99%
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“…The crystal structure of muscovite consists of negatively charged 2:1 layers whose charges are compensated by interlayer cations. Hence, muscovite has a high cation-exchange capacity [18]. Hydration of the interlayer region can cause an increase of the layer spacing, hence the expandable nature of the minerals and easier adsorption by the mucous surface [19].…”
Section: Discussionmentioning
confidence: 99%
“…The most commonly employed preparation procedures for these materials are the use of the sol-gel process for the formation of the inorganic network, the incorporation of preformed dense inorganic structures, such as clusters and particles, and the formation of hybrids using porous or layered inorganic materials either by interpenetration of the organic polymers into the voids, or by exfoliation of the inorganic material [12][13][14]. The unique properties of these materials, such as their high optical transparency, as well as the lack of data on structure-property relationships at a nanoscale, has led to emerging research in this area.…”
Section: Introductionmentioning
confidence: 99%