Continuous and sustainable growth has become a daily norm, putting increasing pressure on organizations to adopt green practices to achieve sustainable competitive advantages. Therefore, this research aimed to analyze the structural relationship between GHRM and GTL on EBs and GIP with the mediating role of EK. The research method was developmental-applied in terms of purpose and descriptive-correlational in terms of research design, using a structural equation modeling approach. The statistical population consisted of all primary school teachers in Urmia city, Iran (Urmia city districts one and two) during the academic year 2022–2023. A one-stage cluster sampling method was used, and the sample size was determined to be 338 individuals using Morgan's table. Standard questionnaires were used to collect the required data, including the questionnaire by Zid et al. (2018) for GHRM, Zhang & Wang (2020) for GTL, Roberson, and Carleton (2018) for EBs, Chen et al. (2013) for GIP, and Me et al. (2012) for EK. Content validity of the research was ensured through the opinions of educational science professors, and the reliability of the questionnaires was confirmed using Cronbach's alpha coefficient, which yielded values of 0.90, 0.77, 0.79, 0.82, and 0.70, respectively. The data were analyzed using Pearson correlation coefficient, structural equation modeling, and confirmatory factor analysis with SPSS 28 and Smart PLS 3 software. The results of the research indicated a significant positive direct relationship between GHRM and GIP. There was a positive direct relationship between GTL and GIP. A positive direct relationship was found between GTL and EBs. However, there was no significant relationship between GHRM and EBs. There was an indirect non-significant relationship between GHRM and EBs with the mediating role of EK. There was no indirect relationship between GTL and GIP with the mediating role of EK. There was no indirect relationship between GTL and EBs with the mediating role of EK.