Abstract:Ring closure reactions O 0130 Domino Reactions that Combine an Azido-Schmidt Ring Expansion with the Diels-Alder Reaction. -Two conceptually different ways concerning the title reaction are investigated, 1. an olefinic azide reacts with unsaturated carbonyl compounds, 2. a substrate containing double bonds, azide and keto function reacts with dienes. A variety of heterocyclic structures is obtained including skeletons of natural products. In the case of azidoketones (XIV) and cyclohexadiene, only the Diels-Ald… Show more
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