2023
DOI: 10.1063/5.0142123
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Doped rare gas clusters up to completion of first solvation shell, CO2–(Rg)n, n = 3–17, Rg = Ar, Kr, Xe

Abstract: Spectra of rare gas atom clusters containing a single carbon dioxide molecule are observed using a tunable mid-infrared (4.3 µm) source to probe a pulsed slit jet supersonic expansion. There are relatively few previous detailed experimental results on such clusters. The assigned clusters include CO2-Arn with n = 3, 4, 6, 9, 10, 11, 12, 15, and 17, as well as CO2-Krn and -Xen with n = 3, 4, and 5. Each spectrum has (at least) partially resolved rotational structure, and each yields precise values for the shift … Show more

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Cited by 4 publications
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