Doping effect on a two-electron silver nanocluster

Yen, Wei-Jung; Liao, Jian-Hong; Chiu, Tzu-Hao; Chen, Jie-Ying; Chen, Yuan Jang; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W.

doi:10.1039/d4nr00326h

Nanoscale

2024

DOI: 10.1039/d4nr00326h

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Doping effect on a two-electron silver nanocluster

Wei-Jung Yen,

Jian-Hong Liao,

Tzu-Hao Chiu

et al.

Abstract: This study investigates the effects of metal addition and doping of a 2-electron silver superatom, [Ag10{S2P(OiPr)2}8] (Ag10). When Ag+ is added to Ag10 in THF solution, [Ag11{S2P(OiPr)2}8(OTf)] (Ag11) is rapidly...

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Cited by 2 publications

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Electronic state modulation of Ag₃₀ nanoclusters within a ring-shaped polyoxometalate

Yanai,

Yonesato,

Kikkawa

et al. 2024

Nanoscale

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Electronic state modulation of Ag₃₀ nanoclusters within a ring-shaped polyoxometalate

Yanai,

Yonesato,

Kikkawa

et al. 2024

Nanoscale

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Conversion mechanism of the atomically precise group IB metal nanoclusters by theoretical calculations

Lv,

Nie,

et al. 2024

Chemical Physics Reviews

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The controllable synthesis and design of group IB metal (i.e., Au/Ag/Cu) and their alloy nanoclusters (IB-NCs) rely on an elucidation of the conversion mechanism, bonding preference, and structure–property relationships. In the past decades, the development of cluster-to-cluster transformation and spectroscopic tracking strategy have provided important mechanistic insights that greatly help researchers improve synthetic skills and explore the application of IB-NCs. Specifically, with the aid of DFT calculations, the structural information of cluster-to-cluster conversion, including the intermediates and active sites, can be deduced from the atomic level. In this review, the conversion mechanisms of IB-NCs in the past three years have been reviewed to summarize the key factors influencing structural transformation and reactivity. The three types of cluster-to-cluster conversion (i.e., foreign metal source, foreign ligand, and other reagents/condition-induced conversion) were highlighted for further synthesis and design of functional nanoclusters.

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Doping effect on a two-electron silver nanocluster

Abstract: This study investigates the effects of metal addition and doping of a 2-electron silver superatom, [Ag10{S2P(OiPr)2}8] (Ag10). When Ag+ is added to Ag10 in THF solution, [Ag11{S2P(OiPr)2}8(OTf)] (Ag11) is rapidly...

Cited by 2 publications

References 69 publications

Electronic state modulation of Ag₃₀ nanoclusters within a ring-shaped polyoxometalate

Electronic state modulation of Ag₃₀ nanoclusters within a ring-shaped polyoxometalate

Conversion mechanism of the atomically precise group IB metal nanoclusters by theoretical calculations

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Doping effect on a two-electron silver nanocluster

Abstract: This study investigates the effects of metal addition and doping of a 2-electron silver superatom, [Ag10{S2P(OiPr)2}8] (Ag10). When Ag+ is added to Ag10 in THF solution, [Ag11{S2P(OiPr)2}8(OTf)] (Ag11) is rapidly...

Cited by 2 publications

References 69 publications

Electronic state modulation of Ag30 nanoclusters within a ring-shaped polyoxometalate

Electronic state modulation of Ag30 nanoclusters within a ring-shaped polyoxometalate

Conversion mechanism of the atomically precise group IB metal nanoclusters by theoretical calculations

Contact Info

Product

Resources

About

Electronic state modulation of Ag₃₀ nanoclusters within a ring-shaped polyoxometalate

Electronic state modulation of Ag₃₀ nanoclusters within a ring-shaped polyoxometalate