On behalf of Daya Bay CollaborationThe precision of neutrino mixing angle θ 13 is of key significance in constraining the leptonic CP phase and testing neutrino oscillation theory. θ 13 is the smallest and the last known neutrino oscillation angle, and its precise measurements were reviewed in this paper. Its two typical measurement approaches, long-baseline accelerator neutrino experiment and short-baseline reactor neutrino experiment, are summarized. Then, their related typical experiments and the corresponding results were also overviewed. Daya Bay is the first experiment to exclude θ 13 =0 with a significance of more than 5 standard deviations and has given the most accurate measurement of sin 2 2θ 13 =0.0841±0.0027(stat.)±0.0019(syst.). In addition, |Δ m |=2.50±0.06 (stat.)± 0.06 (syst.)×10 -3 eV 2 has been also obtained in Daya Bay experiment, which is comparable with Δm measured in long-baseline accelerator neutrino experiment.