Double complex salts based on tetraamminplatinum(ii) and vanadyl(iv) bisoxalate for the preparation of bimetallic Pt–V alloys

Abstract

Oxalate complex of vanadyl(IV) (Bu4N)2[VO(C2O4)2](I) was synthesized and used as a vanadium precursor. The synthesis and characterization of the double complex salts [Pt(NH3)4][VO(H2O)(C2O4)2]∙2H2O(III), {[Pt(NH3)4][VO(C2O4)2]}n(IV) was carried out. The complexes obtained...