We build, using the notion of zinbiel algebra, some commutative sub-algebras C u,v inside an algebra of formal iterated integrals. There is a quotient map from this algebra of formal iterated integrals to the algebra of motivic multiple zeta values. Restricting this quotient map to the sub-algebras C u,v gives a morphism of graded commutative algebras with the same graded dimension. This is conjectured to be generically an isomorphism. When u+v = 0, the image is instead a sub-algebra of the algebra of motivic multiple zeta values.