Various monolayer a-Se-based photoreceptor devices were fabricated by vacuum evaporation and their electrical properties were investigated. Three experimental techniques, namely xerographic time of flight (XTOF), electroded time of flight (TOF) and xerographic discharge were used to determine the drift mobility, carrier lifetime, dark decay and residual voltage. Where possible, these measurements were carried out as a function of applied field and composition, namely As-0.3 wt%, Te up to 17 wt% and Cl up to 60 ppm. The addition of As or Te alone reduced both hole and electron drift mobilities and increased the carrier lifetime. Both XTOF and TOF experiments showed a trap-limited response for electron transport in Se +Cl and Se:Te + Cl systems. The addition of As was found to restore the electron response in these photoreceptors. The drift mobility in all Se-based systems was found to be field dependent, satisfying the algebraic relation p a Y " where n is a constant varying from 0.03 (for electronic mobility in a-Se) to 0.47 (for electron response in a-Se + 17 wt% Tel. Xerographic discharge measurements showed that alloying a-Se with Te increases the dark decay, due to a bulk thermal generation process. Analysing of dark-decay curves indicates that the volume density and energy spread of the mid-gap localised states in a-Se increases with the Te content. The repetition of the xerographic cycle over a number of times leads to the saturation of the residual voltage which was used to calculate the concentration Nt of deep hole traps. The results showed that the addition of Te increases N , from about 1.9 x l O " C ~-~ for a-Se to 7 x l 013 cm-3 for a-Se + 8 wt% Te. From the charge transport data and saturated residual voltage measurements, the hole capture coefficient in a-Se was estimated to be about 1 .O x 1 O-' c& S" .