2022
DOI: 10.1016/j.susc.2022.122042
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DRIFTS investigation of toluene oxidation on CeO2 nanoparticles

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Cited by 16 publications
(1 citation statement)
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“…Menon et al used a transient response technique called the temporal analysis of products to study the detailed mechanism for toluene oxidation over CuO-CeO 2 /Al 2 O 3 ; isotope-exchange experimental products containing 16 O and 18 O when the catalyst was pretreated with 16 O 2 and dioxygen was isotopically labeled with 18 O 2 , indicating that not only gas-phase oxygen but also lattice oxygen is involved in the reaction [32]. Furthermore, infrared Fourier transform spectroscopy (in-situ DRIFTS) and gas chromatography-mass spectroscopy (GC-MS) were performed to identify the by-products and probable reaction pathway in the total oxidation of toluene [33][34][35][36]. However, short-lived intermediates often cannot be detected through experimental processes, and highly complex and overlapping spectra make it difficult to correctly identify the reaction intermediates [37].…”
Section: Introductionmentioning
confidence: 99%
“…Menon et al used a transient response technique called the temporal analysis of products to study the detailed mechanism for toluene oxidation over CuO-CeO 2 /Al 2 O 3 ; isotope-exchange experimental products containing 16 O and 18 O when the catalyst was pretreated with 16 O 2 and dioxygen was isotopically labeled with 18 O 2 , indicating that not only gas-phase oxygen but also lattice oxygen is involved in the reaction [32]. Furthermore, infrared Fourier transform spectroscopy (in-situ DRIFTS) and gas chromatography-mass spectroscopy (GC-MS) were performed to identify the by-products and probable reaction pathway in the total oxidation of toluene [33][34][35][36]. However, short-lived intermediates often cannot be detected through experimental processes, and highly complex and overlapping spectra make it difficult to correctly identify the reaction intermediates [37].…”
Section: Introductionmentioning
confidence: 99%