2019
DOI: 10.1029/2019gc008339
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Dripwater and Calcite Geochemistry Variations in a Monitored Bahamas Cave

Abstract: A cave-monitoring study in Hatchet Bay Cave on the island of Eleuthera, Bahamas, has examined the origins of variations in oxygen and carbon isotopic and minor element composition in cave calcites. Every 3 to 8 months, between 2012 and 2016, temperature, humidity, cave air (δ 13 C CO2 ), dripwaters (δ 18 O and δ 2 H values, and Ca, Sr, and Mg concentrations), and the chemical composition of precipitating calcite (δ 18 O and δ 13 C values, and Ca, Sr, and Mg concentrations) were analyzed in two rooms in the cav… Show more

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Cited by 7 publications
(7 citation statements)
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“…The overall positive correlation of δ 18 O and δ 13 C values with Mg/Ca suggests a strong hydrological control of these proxies, as found in other studies (Arienzo et al, 2019; Cruz et al, 2007; Sinclair et al, 2012; Wassenburg et al, 2019). The weaker correlation of Sr/Ca and Ba/Ca with Mg/Ca indicates that additional processes modulate the incorporation of Sr and Ba in the speleothem, reducing the suitability of these elements as hydrological proxies.…”
Section: Discussionsupporting
confidence: 82%
“…The overall positive correlation of δ 18 O and δ 13 C values with Mg/Ca suggests a strong hydrological control of these proxies, as found in other studies (Arienzo et al, 2019; Cruz et al, 2007; Sinclair et al, 2012; Wassenburg et al, 2019). The weaker correlation of Sr/Ca and Ba/Ca with Mg/Ca indicates that additional processes modulate the incorporation of Sr and Ba in the speleothem, reducing the suitability of these elements as hydrological proxies.…”
Section: Discussionsupporting
confidence: 82%
“…The overall positive correlation of δ 18 O and δ 13 C values with Mg/Ca suggests a strong hydrological control of these proxies, as found in other studies (Arienzo et al, 2019;Cruz et al, 2007;Sinclair et al, 2012;Wassenburg et al, 2019). The weaker correlation of Sr/Ca and Ba/Ca with Mg/Ca indicates that additional processes modulate the incorporation of Sr and Ba in the speleothem, reducing the suitability of these elements as hydrological proxies.…”
Section: Interpretation Of the Climate Proxiessupporting
confidence: 74%
“…We interpret the offset in cluster (1) to reflect a generally weaker convective activity during the last glacial period compared to modern conditions and associated reduced summer rainfall (e.g., Arienzo et al, 2019;Winter et al, 2020;Lases-Hernandez et al, 2019;2020;Bird et al, 2020). Today, Puerto Rico rainfall is isotopically enriched when it is formed by occasional northerly cold fronts as well as orographic processes of trade winds (Scholl and Murphy, 2014).…”
Section: Applicability Of the Oxygen Isotope Equilibrium Thermometermentioning
confidence: 95%
“…In the tropics, the isotopic composition of precipitation, δ 18 Op, has been attributed to changes in precipitation amount and convective activity (Dansgaard, 1964;Lachniet and Patterson, 2009;Vieten et al, 2018a). Consequently, tropical speleothem δ 18 O values are usually interpreted in terms of this isotopic 'amount effect' (Medina-Elizalde et al, 2010;Arienzo et al, 2019;Lases-Hernandez et al, 2019). However, in the soil and karst above the cave as well as at the surface of a stalagmite, various (disequilibrium) isotope fractionation effects can obscure the interpretation of stable isotopes in speleothem calcite (Weber et al, 2021;Hansen et al, 2019;Carlson et al, 2020).…”
Section: Introductionmentioning
confidence: 99%