Because of its critical role in tropical storm events, rainfall over sea surface has always been an important subject for remote sensing. Recently, space-borne high-resolution synthetic aperture radar (SAR) has been found to be a potential tool for rainfall observation. However, many interesting phenomenon of rain-wind over sea surface as revealed by SAR images are still not fully understood. This paper attempts to develop a physics-based radiative transfer model to capture the scattering behavior of rainfall over rough sea surface. Raindrop scattering and attenuation is modeled as Rayleigh spherical particle, while rain-induced rough surface is described by the Log-Gaussian ring-wave spectrum. The model is compared with empirical models and measurements.