1993
DOI: 10.2355/isijinternational.33.307
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Dross Phases Formed in Galvanizing Baths Containing(0-0.1)wt% Nickel at 450.DEG.C..

Abstract: The structure and composition of the intermetallic dross phases formed in zinc baths containing

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Cited by 17 publications
(5 citation statements)
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“…The results of elemental analysis of the dross crystals were compared with elemental composition of the known Ni-Zn-Fe phase [4]. We can conclude that the dross crystals are the crystals of modified ζ-phase, the FeZn13, where 0.5% iron is substituted by nickel atoms.…”
Section: Discussionmentioning
confidence: 98%
See 1 more Smart Citation
“…The results of elemental analysis of the dross crystals were compared with elemental composition of the known Ni-Zn-Fe phase [4]. We can conclude that the dross crystals are the crystals of modified ζ-phase, the FeZn13, where 0.5% iron is substituted by nickel atoms.…”
Section: Discussionmentioning
confidence: 98%
“…Two intermetallic Ni-Zn-Fe phases are present in this dross. These phases were identified as ζ-phase and Γ2-phase [4]. Phase ζ contains about 0.5 at.% nickel and isomorphic FeZn13.…”
Section: Introductionmentioning
confidence: 99%
“…As a result, they are easily torn out when the product is withdrawn from the bath, causing defects on the surface of the coating and increasing the amount of zinc drawn from the bath. The formation of C 2 phase particles also consumes nickel for their creation (Ref 10,11). Nickel, although it is a permanent additive, requires strict control of the content in the bath and refilling to the optimal level.…”
Section: The Role Of Alloying Additives In a Zinc Bathmentioning
confidence: 99%
“…Excessive Ni content in the bath causes floating dross, which contaminates the bath [41]. Floating dross is formed by fine particles of the Γ 2 phase described by the Fe 6 Ni 5 Zn 89 formula, which is isostructural with the Γ phase of the Fe-Zn binary system [42]. In the Fe-Ni-Zn triple equilibrium system [43], the Γ 2 phase is stable at Ni content over 0.06 wt %.…”
Section: Effect Of Nickelmentioning
confidence: 99%