Dry reforming of methane on Ni-Fe-MgO catalysts: Influence of Fe on carbon-resistant property and kinetics

Zhang, Tingting; Liu, Zhongxian; Zhu, Yi‐An; Liu, Zhicheng; Sui, Zhi‐Jun; Zhu, Kake

doi:10.1016/j.apcatb.2019.118497

Cited by 147 publications

(90 citation statements)

References 73 publications

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“…In order to reduce coke formation and improve catalyst stability/activity, numerous strategies involving modification in the catalyst surface composition and metalsupport interaction have been attempted. 219,220,222,[356][357][358][359][360][361][362][363][364][365][366][367][368] To develop a coke-resistant catalyst, approaches based on selective blockage of the defect sites of the active metal (e.g., Ni) nanoparticles by the use of inert elements such as S, 330 Sn, 369 Au, 370 and K (ref. 234 and 371) were attempted.…”

Section: Catalysis Science and Technologymentioning

confidence: 99%

Mechanistic and multiscale aspects of thermo-catalytic CO₂conversion to C₁products

Alam

Cheula

Moroni

et al. 2021

Catal. Sci. Technol.

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Section: Catalysis Science and Technologymentioning

confidence: 99%

Mechanistic and multiscale aspects of thermo-catalytic CO₂conversion to C₁products

Alam

Cheula

Moroni

et al. 2021

Catal. Sci. Technol.

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“…Significant advances on the catalyst development have been made to reduce the carbon deposition. Incorporation of appropriate metals (e.g., La, Fe, Sn, and Zr) (Chen et al, 2020;Li et al, 2020;Zhang et al, 2020aZhang et al, , 2020b to Ni-based catalysts has proven to improve the coke-resistance property. Some catalysts (e.g., Ni-Mg PSNTS) showed a high coke rate up to 0.022 g coke /(g cat *h).…”

Section: Reviewmentioning

confidence: 99%

Biogas Reforming to Syngas: A Review

et al. 2020

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Interest in novel uses of biogas has increased recently due to concerns about climate change and greater emphasis on renewable energy sources. Although biogas is frequently used in low-value applications such as heating and fuel in engines or even just flared, reforming is an emerging strategy for converting biogas to syngas, which could then be used to obtain high-value-added liquid fuels and chemicals. Interest also exists due to the role of dry, bi-, and tri-reforming in the capture and utilization of CO 2 . New research efforts have explored efficient and effective reforming catalysts, as specifically applied to biogas. In this paper, we review recent developments in dry, bi-, and tri-reforming, where the CO 2 in biogas is used as an oxidant/ partial oxidant. The synthesis, characterization, lifetime, deactivation, and regeneration of candidate reforming catalysts are discussed in detail. The thermodynamic limitation and techno-economics of biogas conversion are also discussed.

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“…The introduction of Fe reduced the content of Ni, which resulted in a lower expense of catalyst synthesis. Moreover, according to the catalytic evaluations in Zhang et al's study [20], the activity of the Ni surface was passivated by Fe, which led to a reduction in the coke-tolerant property. The characterization of catalysts suggested that compared with single metal, the alloying of Fe with Ni enhanced the thermal stability and inhibited the thermal sintering.…”

Section: Introductionmentioning

confidence: 99%

Dynamic Pyrolysis Characteristics, Kinetics and Products Analysis of Waste Tire Catalytic Pyrolysis with Ni/Fe-ZSM-5 Catalysts Using TG-IR-GC/MS

Zhang

et al. 2021

Catalysts

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Catalysts are usually used in the thermal conversion of waste tires to enhance the efficiency of the process and the quality of pyrolytic products. Recently, it has already been proved that Ni/Fe bimetallic catalysts had an effective catalytic effect on the thermal decomposition of organic solid wastes. Herein, we employed a TG-IR-GC/MS system to investigate the kinetics and product analysis of waste tire catalytic pyrolysis using Ni/Fe bimetallic ZSM-5 as catalysts. Iso-conversional methods and master-plot methods were employed to estimate the activation energies and reaction model of waste tire catalytic pyrolysis. The results illustrated that the ZSM-5 loading with 7 wt.% Ni and 3 wt.% Fe had the best catalytic effect on decreasing the activation energies with a reduction of 13%. The determination of kinetic models showed that both non-catalyzed and catalyzed pyrolysis were fitted to a Fn model while the addition of a catalyst reduced the reaction order to varying degrees. Both FTIR and GC/MS results suggested that the metallic Ni-based catalyst had strong ability to transform alkenes into aromatic hydrocarbons. Ni/Fe bimetallic catalysts showed almost the same catalytic performance as the Ni metallic catalyst, which could reduce the cost of the catalyst. Thus, this study could deepen the understanding and provide a basic guideline of Ni/Fe bimetallic catalysts on the catalytic pyrolysis process of waste tires.

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Dry reforming of methane on Ni-Fe-MgO catalysts: Influence of Fe on carbon-resistant property and kinetics

Cited by 147 publications

References 73 publications

Mechanistic and multiscale aspects of thermo-catalytic CO₂conversion to C₁products

Mechanistic and multiscale aspects of thermo-catalytic CO₂conversion to C₁products

Biogas Reforming to Syngas: A Review

Dynamic Pyrolysis Characteristics, Kinetics and Products Analysis of Waste Tire Catalytic Pyrolysis with Ni/Fe-ZSM-5 Catalysts Using TG-IR-GC/MS

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Dry reforming of methane on Ni-Fe-MgO catalysts: Influence of Fe on carbon-resistant property and kinetics

Cited by 147 publications

References 73 publications

Mechanistic and multiscale aspects of thermo-catalytic CO2conversion to C1products

Mechanistic and multiscale aspects of thermo-catalytic CO2conversion to C1products

Biogas Reforming to Syngas: A Review

Dynamic Pyrolysis Characteristics, Kinetics and Products Analysis of Waste Tire Catalytic Pyrolysis with Ni/Fe-ZSM-5 Catalysts Using TG-IR-GC/MS

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Mechanistic and multiscale aspects of thermo-catalytic CO₂conversion to C₁products

Mechanistic and multiscale aspects of thermo-catalytic CO₂conversion to C₁products