Novel bimodal size ranges of ceramic particles (SiC (115 μm)and SiO 2 (1.2 μm) (labelled as SIL)), SiC (115 μm) and mullite (4 μm) (labelled as MUL)) iron matrix composite structures were processed by powder metallurgy. The physical, mechanical and tribological properties were evaluated for these composites. The dry sliding wear and friction tests were conducted at ambient temperature and 60% humidity in a laboratory scale dynamometer for braking material applications. We have selected four braking speeds (5, 10, 15 and 20 m/s) and two braking loads (100 and 200 N) to cover the broad spectrum of braking conditions experienced in a typical automobile and military aircrafts. The particle morphology, microstructure, wear surface morphology and mechanisms were discussed based on the scanning electron microscopy equipped with energy-dispersive spectroscopy, optical microscope and stereoscope examinations. Our work provides the following important results: (1) bimodal particle structure composites can be easily fabricated using powder metallurgy, (2) the wear resistance and the braking performance of bimodal particle-reinforced composites is superior than the typical automobile asbestos or non asbestos, metallic, semi-metallic and Al/SiC composites based brake materials, (3) Between mullite and silica reinforcements, the mullite-reinforced bimodal composite (MUL) provides higher wear resistance, braking performance (high friction coefficient, stopping distance, stopping time), higher flexural strength, stiffness and hardness. These improvements are attributed to the better powder consolidation, high elastic modulus of mullite and better distribution of mullite in the iron matrix, (4) Increasing sliding speed decreases the wear rate and increases the friction coefficient in the MUL composites, whereas the variations in the wear rate and the friction coefficient are random in the SIL composites and (5) the combined effects of abrasive, delamination, oxidation and tribofilm-controlled wear mechanisms are observed to be operative at all sliding speeds and load conditions for both the composites.