2010
DOI: 10.1007/978-90-481-2845-7_3
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Drying of Latex Films

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Cited by 7 publications
(10 citation statements)
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“…These coalescing aids, which are generally organic molecules of low molar mass, plasticize the hard polymer phase, reducing the T g and therefore the MFFT of the latex. Once the film is produced, the coalescing aids evaporate, leaving behind a film with high modulus . However, this approach, even if effective, results in the release of organic coalescing aids to the atmosphere, thus masking the environmental benefits of waterborne coatings.…”
Section: Fundamental Challenges In the Production Of Emulsion Polymersmentioning
confidence: 99%
See 2 more Smart Citations
“…These coalescing aids, which are generally organic molecules of low molar mass, plasticize the hard polymer phase, reducing the T g and therefore the MFFT of the latex. Once the film is produced, the coalescing aids evaporate, leaving behind a film with high modulus . However, this approach, even if effective, results in the release of organic coalescing aids to the atmosphere, thus masking the environmental benefits of waterborne coatings.…”
Section: Fundamental Challenges In the Production Of Emulsion Polymersmentioning
confidence: 99%
“…The film formation process of colloidal polymers is constituted by three main steps that are water evaporation, particle deformation, and finally coalescence and interdiffusion of polymer chains between neighboring particles (see Figure 4 ). 115 As these last steps require the polymer to be in a relatively soft state, i.e., above its glass transition temperature ( T g ), the minimum temperature at which a film can be formed (minimum film formation temperature, MFFT) is closely related to the T g of the polymer forming the film.…”
Section: Fundamental Challenges In the Production Of Emulsion Polymersmentioning
confidence: 99%
See 1 more Smart Citation
“…8−11 The transformation of polymer latexes to their final dried polymer latexes (e.g., films) is often a key aspect of commercial processes. 12 For successful film formation, the particles must be able to deform, coalesce, and undergo interdiffusion. 13 These steps require the polymer particles to have a soft phase where the glass transition temperature (T g ) is below the application temperature.…”
Section: ■ Introductionmentioning
confidence: 99%
“…In practice, coating formulations are not simple binary blends of hard spheres. For example, along with the binder and pigment, a realistic paint formulation contains around 10–15 different additives such as defoamers, wetting agents, and dispersants . These components can significantly alter particle–particle interactions, which in turn can significantly alter the degree and type of stratification. , To bring the self-stratification method closer to paint and coating applications, the influence of these additives on the assembly process needs to be ascertained.…”
Section: Introductionmentioning
confidence: 99%