Using nonedible waste frying oil (WFO) as biodiesel and hydrogen in the mix composition may partly replace significant quantities of diesel fuel and help reduce fossil fuel reliance. The combination of diesel fuel, waste‐fired biodiesel, and hydrogen gas can improve the performance, combustion, and emissions of single‐fuel and dual‐fuel diesel engines. This may lead to a novel alternative fuel mix pattern and modification for diesel engines, which is the research gap. Although there has been some research on waste‐fired biodiesel and hydrogen gas‐powered dual‐fuel engines with the goal of partly replacing fossil fuels to a larger degree, there has been very little progress in this area. As a result, the current research effort focuses on using diesel fuel (100%, 30%, and 60%), waste‐fired biodiesel (at 100%, 70%, and 40%), and hydrogen gas as fuel sources (5 and 10 liters per minute [LPM]). According to the current experiment, it was perceived in both dual‐fuel and single‐fuel modes. Under duel‐fuel mode, the engine results for WFOB70D30 + H10 fuel blend had higher 4.2% (brake thermal efficiency [BTE]), 19.72% (oxides of nitrogen [NOx]), and 9.09% (ignition delay [ID]) with a minimal range of (in‐cylinder pressure, MFB, volumetric efficiency and heat release rate [HRR]) and a dropped rate of 4.34% (brake‐specific energy consumption [BSEC]), 33.33% (carbon monoxide [CO]), 39.28% (hydrocarbons [HC]), 9.43% (smoke), and 6.97% (combustion duration [CD]) related to diesel fuel at peak load. However, single‐fuel powered diesel engines provide minimal performance for the WFOB40D60 fuel blend with (11.32% lower BTE and 2.04% higher BSEC) and minimal rate of combustion (lower cylinder pressure, 2.12% minimal CD, 14.72% higher ID, minimal HRR combustion, volumetric efficiency, and MFB). Emitted fewer emissions (9.09% less CO, 4.87% less HC, 0.92% higher NOx, and 1.69% more smoke) than diesel fuel at peak load. Therefore, it was concluded that adding 10 LPM of hydrogen gas to the biodiesel under a dual‐fuel condition leads to better combustion, better performance, and less pollution than the single‐fuel mode of operation.