Dual nucleation sites induced by ZIF-67 towards mismatch of polyphosphazene hollow sub-micron polyhedrons and nanospheres in flame retardant epoxy matrix

Song, Xiping; Hou, Boyou; Han, Zhengde; Pan, Ye‐Tang; Geng, Zhishuai; Ibarra, Laia Haurie; Zhang, Zhida

doi:10.1016/j.cej.2023.144278

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Industrial Chemistry and Materials1

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Cited by 22 publications

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“…3g-i). 50 The as-prepared fillers not only imparted excellent flame-retardant properties to the epoxy composites (Fig. 3j and k), but also improved the mechanical properties significantly.…”

Section: Industrial Chemistry and Materialsmentioning

confidence: 88%

Coordination bond cleavage of metal–organic frameworks and application to flame-retardant polymeric materials

Song,

Pan,

et al. 2024

Ind. Chem. Mater.

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Section: Industrial Chemistry and Materialsmentioning

confidence: 88%

Coordination bond cleavage of metal–organic frameworks and application to flame-retardant polymeric materials

Song,

Pan,

et al. 2024

Ind. Chem. Mater.

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Joint Exfoliation of MXene by Dimensional Mismatched SiC/ZIF‐67 Toward Multifunctional Flame Retardant Thermoplastic Polyurethane

Bi,

Song,

Zhang

et al. 2024

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The single‐layer MXene fully demonstrates the advantages of 2D materials, especially catalytic, conductive, and mechanical properties. However, the high energy consumption and low efficiency faced by MXene in the divestiture process are still challenges that need to be solved urgently. In this article, dimension mismatch and collaborative stripping strategies are skillfully combined to easily realize the transformation from multi‐layer MXene to single layer. In addition, the functionalized MXene@SiC@polyaniline (MXene@SiC@PANI) nano‐hybrid materials are used as fillers to improve the thermal conductivity, flame retardant, and antibacterial properties of thermoplastic polyurethane (TPU). The surface temperature of TPU/MXene@SiC@PANI composites increased from 33.4 °C to 59.8 °C within 10 s. In addition, the antibacterial efficiency of TPU composites against Escherichia coli and Staphylococcus aureus is 69.6% and 88.9%, respectively. Compared with pure TPU, the peak heat release rate and total heat release are reduced by 71.4% and 34.6%, respectively. The flame‐retardant mechanism of MXene hybrid materials is systematically discussed. It is worth noting that the introduction of PANI enhances the compatibility between the filler and the polymer, effectively maintaining the mechanical properties of the TPU itself. This work provides a convenient method for the multi‐functional practical application of TPU.

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Design of covalent adaptable networks with intrinsic flame retardancy

Zu,

Geng,

Yang

2024

Polym. Bull.

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Dual nucleation sites induced by ZIF-67 towards mismatch of polyphosphazene hollow sub-micron polyhedrons and nanospheres in flame retardant epoxy matrix

Cited by 22 publications

References 46 publications

Coordination bond cleavage of metal–organic frameworks and application to flame-retardant polymeric materials

Coordination bond cleavage of metal–organic frameworks and application to flame-retardant polymeric materials

Joint Exfoliation of MXene by Dimensional Mismatched SiC/ZIF‐67 Toward Multifunctional Flame Retardant Thermoplastic Polyurethane

Design of covalent adaptable networks with intrinsic flame retardancy

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