Dual Role of Alkynyl Bromides in One-Step Synthesis of Bromo-Substituted Alkynyl Sulfides. -The first additive-free method for the formation of bromo-substituted alkynyl sulfides (III) is reported. -(YANG, Y.; HUANG, H.; LIU, W.; LIANG*, Y.; Synth. Commun. 45 (2015) 1, 86-93, http://dx.