Dummy molecularly imprinted membranes based on an eco-friendly synthesis approach for recognition and extraction of enrofloxacin and ciprofloxacin in egg samples

Yuan, Yue; Yuan, Xucan; Hang, Qian; Zheng, Runjiao; Lin, Longyi; Zhao, Longshan; Xiong, Zhili

doi:10.1016/j.chroma.2021.462411

Cited by 17 publications

(7 citation statements)

References 39 publications

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“…92 Furthermore, Yuan et al prepared MIAMs using the nylon-66 (NY-66) membranes with two functional monomers, methacrylate (MA) and 1-vinylimidazole (1-VM), for the identification of enrofloxacin (ENR) and ciprofloxacin (CIP) in egg samples. 93 The sensor shows high sensitivity results, good recovery, and a low detection limit. The results were related to the characteristics of MIAMs possessing a rough surface with a large surface area and specific sites to distinguish the target molecule.…”

Section: Sensor-based Miammentioning

confidence: 97%

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Molecularly Imprinted Affinity Membrane: A Review

et al. 2022

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A molecularly imprinted affinity membrane (MIAM) can perform separation with high selectivity due to its unique molecular recognition introduced from the molecular-printing technique. In this way, a MIAM is able to separate a specific or targeted molecule from a mixture. In addition, it is possible to achieve high selectivity while maintaining membrane permeability. Various methods have been developed to produce a MIAM with high selectivity and productivity, with their respective advantages and disadvantages. In this paper, the MIAM is reviewed comprehensively, from the fundamentals of the affinity membrane to its applications. First, the development of a MIAM and various preparation methods are presented. Then, applications of MIAMs in sensor, metal ion separation, and organic compound separation are discussed. The last part of the review discusses the outlook of MIAMs for future development.

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Section: Sensor-based Miammentioning

confidence: 97%

“…Furthermore, Yuan et al prepared MIAMs using the nylon-66 (NY-66) membranes with two functional monomers, methacrylate (MA) and 1-vinylimidazole (1-VM), for the identification of enrofloxacin (ENR) and ciprofloxacin (CIP) in egg samples . The sensor shows high sensitivity results, good recovery, and a low detection limit.…”

Section: Sensor-based Miammentioning

confidence: 99%

Molecularly Imprinted Affinity Membrane: A Review

et al. 2022

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“…The selectivity provided by the DES-MIP was good enough to allow the purification of chlorogenic acid from honeysuckle. Similarly, Tang et al [47] evaluated three different DES as an auxiliary solvent in the synthesis of chloramphenicolimprinted polymers. Three different HBDs were tested (ethylene glycol, glycerol, or propylene glycol) combined with choline chloride as HBA.…”

Section: Deep Eutectic Solventsmentioning

confidence: 99%

Recent advances and future trends in molecularly imprinted polymers‐based sample preparation

Díaz‐Álvarez¹,

Turiel²,

Martín‐Esteban³

2023

J of Separation Science

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Molecular imprinting technology is a well‐established technique for the obtainment of tailor‐made polymers, so‐called molecularly imprinted polymers, with a predetermined selectivity towards a target analyte or structurally related compounds. Accordingly, molecularly imprinted polymers are considered excellent materials for sample preparation providing unprecedented selectivity to analytical methods. However, the use of molecularly imprinted polymers in sample preparation still presents some shortcomings derived from the synthesis procedure itself limiting its general applicability. In this regard, molecularly imprinted polymers use to display binding sites heterogeneity and slow diffusion mass transfer of analytes to the imprinted sites affecting their overall performance. Besides, the performance of molecularly imprinted polymers in organic solvents is excellent, but their selective binding ability in aqueous media is considerably reduced. Accordingly, the present review pretends to provide an updated overview of the recent advances and trends of molecularly imprinted polymers‐based extraction, focusing on those strategies proposed for the improvement of mass transfer and selective recognition in aqueous media. Besides, with the progressive implementation of Green Chemistry principles, the different steps and strategies for the preparation of molecularly imprinted polymers are reviewed from a green perspective.

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“…Recently, in an eco-friendly synthesis involving the use of 1-vinylimidazole as a functional monomer and mild photo-co-polymerization conditions on the surface of a nylon-66 membrane, gatifloxacin was used as a dummy template. The prepared composite MIMs allowed for the simultaneous recognition and extraction of the antibiotics enrofloxacin and ciprofloxacin from egg samples [ 281 ].…”

Section: Green Molecularly Imprinted Membranesmentioning

confidence: 99%

Green Chemistry and Molecularly Imprinted Membranes

et al. 2022

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Technological progress has made chemistry assume a role of primary importance in our daily life. However, the worsening of the level of environmental pollution is increasingly leading to the realization of more eco-friendly chemical processes due to the advent of green chemistry. The challenge of green chemistry is to produce more and better while consuming and rejecting less. It represents a profitable approach to address environmental problems and the new demands of industrial competitiveness. The concept of green chemistry finds application in several material syntheses such as organic, inorganic, and coordination materials and nanomaterials. One of the different goals pursued in the field of materials science is the application of GC for producing sustainable green polymers and membranes. In this context, extremely relevant is the application of green chemistry in the production of imprinted materials by means of its combination with molecular imprinting technology. Referring to this issue, in the present review, the application of the concept of green chemistry in the production of polymeric materials is discussed. In addition, the principles of green molecular imprinting as well as their application in developing greenificated, imprinted polymers and membranes are presented. In particular, green actions (e.g., the use of harmless chemicals, natural polymers, ultrasound-assisted synthesis and extraction, supercritical CO2, etc.) characterizing the imprinting and the post-imprinting process for producing green molecularly imprinted membranes are highlighted.

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Dummy molecularly imprinted membranes based on an eco-friendly synthesis approach for recognition and extraction of enrofloxacin and ciprofloxacin in egg samples

Cited by 17 publications

References 39 publications

Molecularly Imprinted Affinity Membrane: A Review

Molecularly Imprinted Affinity Membrane: A Review

Recent advances and future trends in molecularly imprinted polymers‐based sample preparation

Green Chemistry and Molecularly Imprinted Membranes

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