Recent advances in the study on the structural, dynamic and functional properties of polymeric colloidal crystals, mainly in the deionized aqueous suspension, are reviewed. Several important findings are paid attention: (a) Soft‐type colloidal crystallization takes place by the interparticle
repulsion
originated from the extended electrical double layers. The interaction is opposite to the importance of the interparticle
attraction
for crystallization of other general crystals, metals, proteins, and ice, for example. (b) Main lattice structures are face‐centered‐cubic (
fcc
) and body‐centered‐cubic (
bcc
) lattices. Packing efficiency, that is, minimizing the free volume is important. (c) Giant‐sized single crystals from the homogeneous and heterogeneous nucleation mechanisms form at the deionized and very diluted aqueous suspensions of monodisperse colloidal spheres. (d) Classical theory of crystallization holds for colloidal crystallization. (e) Viscosity, elasticity, and viscoelasticity of colloidal crystals are reviewed. (f) External field effects (gravitational, electrical, centrifugal forces, and so on) are discussed. (g) Colloidal crystal structure, morphology, and kinetics are quite similar to those of general crystals. (h) The application of colloidal crystals is also reviewed briefly.