In the quest for sustainable energy solutions to meet
the growing
energy demands, third-generation solar photovoltaic (PV) technologies,
specifically dye-sensitized solar cells (DSSCs), have gained considerable
attention for their cost-effectiveness, ease of manufacture, and operability
under dim-light conditions. However, the limited light-harvesting
capability of mesoporous titanium dioxide (m-TiO2) photoanodes
presents a significant hurdle, constraining the power conversion efficiency
(PCE) of the DSSCs. The present work introduces a class of semiconducting
materials known as sulvanites, with a particular focus on Cu3VSe4, which is aimed at addressing the light-harvesting
issues encountered with m-TiO2. Cu3VSe4 exhibits a broad absorption across the visible range of solar spectrum,
which substantially enhances light absorption in DSSCs, when incorporated
into m-TiO2 photoanodes. Cu3VSe4 nanocrystals,
synthesized via a hot injection, one-pot synthesis method, are incorporated
in m-TiO2 (Cu3VSe4/m-TiO2) via direct chemical mixing. To understand the induced changes in
the structural and optical properties of m-TiO2 by incorporating
Cu3VSe4 nanocrystals, the prepared thin films
are characterized using scanning electron microscopy (SEM), Brunauer–Emmett–Teller
(BET), attenuated total reflectance (ATR), UV–vis, and Raman
spectroscopy. DSSCs employing Cu3VSe4/m-TiO2 photoanodes demonstrated a noteworthy 14.28% increase in
PCE (reaching 7.38%) compared to that of reference m-TiO2 DSSCs (6.37%). The enhanced PCE is attributed to the improved light
absorption of photoanodes resulting from enhanced porosity and dye-loading
content of Cu3VSe4/m-TiO2 photoanodes
and improved charge-transfer processes. The improved charge-transport
kinetics of fabricated DSSCs is confirmed from the reduced resistances
at different interfacial layers estimated from the electrochemical
impedance spectroscopy (EIS) spectra. Furthermore, external quantum
efficiency (EQE) spectra indicate an improved spectral response of
Cu3VSe4/m-TiO2 photoanodes in DSSCs.
Hence, the incorporation of sulvanites offers a promising strategy
to enhance the light-harvesting efficiency not only in DSSCs but also
in various cutting-edge optoelectronic devices.