DyF3: An Efficient Electrocatalyst for N2 Fixation to NH3 under Ambient Conditions

Li, Yuanfang; Li, Tingshuai; Zhu, Xiaojuan; Alshehri, Abdulmohsen Ali; Alzahrani, Khalid Ahmed; Lu, Siyu

doi:10.1002/asia.201901624

Cited by 37 publications

(10 citation statements)

References 66 publications

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“…The anodic electrocatalytic oxidation (ECO) reaction plays a crucial part in this field and is investigated extensively. [9,11,12] The oxygen evolution reaction (OER), a general anodic halfreaction, serves as the counter electrode in a series of electrocatalytic conversion technologies, such as electrocatalytic water splitting, [13,14] carbon dioxide reduction reaction (CO 2 RR), [15,16] nitrogen reduction reaction (NRR), [17][18][19] and nitrate reduction reaction (NO 3 − RR), [20][21][22] etc. Nevertheless, the sluggish kinetics of anodic OER leads to high overpotential, which largely restricts the overall electrocatalytic reaction rate.…”

mentioning

confidence: 99%

Recent Advances on Electrolysis for Simultaneous Generation of Valuable Chemicals at both Anode and Cathode

Xiang

Peng

et al. 2021

Advanced Energy Materials

172

123

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Affected by both the energy shortage and environmental crisis, the development of electrocatalytic conversion process powered by renewable energy (wind, solar, tide, etc.) has received considerable attention. [1][2][3][4][5] Generally, electrocatalytic reactions involve To make efficient use of electrical energy in the whole electrocatalysis conversion process, the integrating of anode and cathode reactions plays a vital role. The combination of electrocatalytic anodic oxidation with cathodic reduction can not only maximize the return of energy investment, but also produces value-added materials on both sides. Herein, in this review, recent advances in co-electrolysis processes for valuable chemical production are systematically summarized. To be more specific, the popular hydrogen evolution reaction, carbon dioxide reduction reaction, nitrogen reduction reaction as well as nitrate reduction reaction integrated with anodic oxidation reactions to valueadded products, respectively are comprehensively reviewed, and then other paired electrolysis systems (especially for biomass-based compounds) toward high-value-added chemical generation are discussed in detail. This review sheds light on the integration of electrocatalytic reductions and oxidation reactions to develop high-value substances. To benefit researchers and facilitate the progress in this field, the challenges and future prospects for these integrated reactions are also proposed.

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mentioning

confidence: 99%

Recent Advances on Electrolysis for Simultaneous Generation of Valuable Chemicals at both Anode and Cathode

Xiang

Peng

et al. 2021

Advanced Energy Materials

172

123

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“…Sun et al proposed DyF 3 as active NRR electrocatalyst. [ 265 ] When tested in 0.1 m Na 2 SO 4 , DyF 3 delivered 8.8% efficiency at −0.45 V. This work not only shows Dy is NRR active catalyst but also opens a new window to extend the work on Dy and other lanthanides.…”

Section: Transition Metals or Elementsmentioning

confidence: 78%

Exploration and Investigation of Periodic Elements for Electrocatalytic Nitrogen Reduction

Patil

Wang

2020

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“…Besides Fe and Mo, Zr, Ti, Nb, Co, [44] Ni, [45] and Dy [46] are also reported in NRR. Xian et al reported that 8 mol% Y 2 O 3 doped zirconia nanoparticles (8YSZ-NPs) were used as a noble-metal free catalyst for the conversion of nitrogen to ammonia, achieving high faradic efficiency of 12.3% and an NH 3 yield of 10.84 μg h À 1 mg cat À 1 in 0.1 M Na 2 SO 4 .…”

Section: Other Transition Metal Containing Catalystsmentioning

confidence: 96%

Recent Advances in Noble‐Metal‐Free Catalysts for Electrocatalytic Synthesis of Ammonia under Ambient Conditions

Xiang

Wang

et al. 2020

Chemistry An Asian Journal

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Ammonia is an essential chemical for producing fertilizers and energy carriers. However, the industrial Haber-Bosch process causes huge CO 2 emissions and energy waste. As a promising alternative for Haber-Bosch process, electrochemical synthesis of ammonia has drawn much attention. Catalysts, as a vital part of electrochemical nitrogen reduction reaction (NRR), have developed rapidly in recent years. Compared to noble-metal catalysts, noble-metal-free catalysts possess a low-cost advantage. In this review, noble-metalfree catalysts, including metal-based materials, metal organic frameworks (MOFs), MXenes, and metal-free materials, are summarized. In addition, effective design strategies are discussed, along with the main problems and some potential directions of noble-metal-free NRR catalysts. 2. Advances in Noble-Metal-Free Catalysts for Electrocatalytic N 2 Reduction Recently, although noble metal catalysts have better catalytic performance in NRR, researchers have paid more attention to the utilization of resource-rich elements in the earth, including iron, molybdenum, carbon, nitrogen, boron and other nonnoble elements, in order to reduce costs and improve the [a

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DyF₃: An Efficient Electrocatalyst for N₂ Fixation to NH₃ under Ambient Conditions

Cited by 37 publications

References 66 publications

Recent Advances on Electrolysis for Simultaneous Generation of Valuable Chemicals at both Anode and Cathode

Recent Advances on Electrolysis for Simultaneous Generation of Valuable Chemicals at both Anode and Cathode

Exploration and Investigation of Periodic Elements for Electrocatalytic Nitrogen Reduction

Recent Advances in Noble‐Metal‐Free Catalysts for Electrocatalytic Synthesis of Ammonia under Ambient Conditions

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