Dynamic Buffer Capacities in Redox Systems

Abstract

The buffer capacity concept is extended on dynamic redox systems, realized according to titrimetric mode, where changes in pH are accompanied by changes in potential E values; it is the basic novelty of this paper. Two examples of monotonic course of the related curves of potential E vs. and pH vs. Φ relationships were considered. The systems were modeled according to GATES/GEB principles.

The Distinguishing Role of 2.f(O) - f(H) in Electrolytic Systems

“…Some kinetic effects involved with organic compounds can also be tested [39]. The dynamic buffer capacities [40] in the form analogous to dynamic buffer capacity in acid-base systems [41,42] were also formulated. From the GATES/GEB [1,[3][4][5][6][7][8][10][11][12][13][14][15][16][43][44][45][46] viewpoint, the terms: oxidation number, oxidant and reductant, equivalent mass [8] are derivative terms [47], not necessary (not applicable) for considerations on a redox system.…”