Dynamic Entwined Topology in Helical Covalent Polymers Dictated by Competing Supramolecular Interactions
Lacey J. Wayment,
Simon J. Teat,
Shaofeng Huang
et al.
Abstract:Naturally occurring polymeric structures often consist of 1D polymer chains intricately folded and entwined through non‐covalent bonds, adopting precise topologies crucial for their functionality. The exploration of crystalline 1D polymers through dynamic covalent chemistry (DCvC) and supramolecular interactions represents a novel approach for developing crystalline polymers. This study shows that sub‐angstrom differences in the counter‐ion size can lead to various helical covalent polymer (HCP) topologies, in… Show more
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