<p>In recent years, long-range wide-area networks (LoRaWAN) have gained much attention as low-power wide-area networks. LoRaWAN uses ALOHA as the medium access control protocol, where the end devices transmit data randomly and retransmit it up to eight times if collisions occur. ALOHA is not energy efficient and works perfectly for a smaller network. Several techniques, including the use of synchronization and scheduling schemes, to deal with the limitations imposed by ALOHA in LoRaWAN have been reported in the literature. However, the existing synchronization and scheduling algorithms transmit synchronization messages randomly using one super frame with fixed time slots that accommodate devices using different spreading factors, which limit the LoRaWAN network's scalability. This work proposes a slotted synchronization mechanism for transmitting synchronization requests to the gateway. The performance of the slotted synchronization was evaluated through simulation using packet delivery ratio (PDR) and energy efficiency as the performance parameters. The results indicate that when the number of devices in the network increases, a time-slotted synchronization consumes less energy, on average, by about 0.2 mAh. The use of a slotted synchronization can improve the energy efficiency of the end devices as collisions are completely avoided, achieving a PDR of 100%.</p>