Demand response is
a viable concept to deal with and benefit from
fluctuating electricity prices and is of growing interest to the electrochemical
industry. To assess the flexibility potential of such processes, a
generic, interdisciplinary methodology is required. We propose such
a methodology, in which the electrochemical fundamentals and the theoretical
potential are determined first by analyzing strengths, weaknesses,
opportunities, and threats. Afterward, experiments are conducted to
determine selectivity and yield under varying loads and to assess
the additional long-term costs associated with flexible operation.
An industrial-scale electrochemical process is assessed regarding
its technical, economic, and practical potential. The required steps
include a flow sheet analysis, the formulation and solution of a simplified
model for operation scheduling under various business options, and
a dynamic optimization based on rigorous, dynamic process models.
We apply the methodology to three electrochemical processes of different
technology readiness levelsthe syntheses of hydrogen peroxide,
adiponitrile, and 1,2-dichloroethane via chloralkali electrolysisto
illustrate the individual steps of the proposed methodology.