As human civilization progressed and economic growth accelerated, researchers focused on creating comfortable living conditions to satisfy the growing requirements for cooling. [1][2][3][4] Active cooling apparatuses, such as air conditioners, have been broadly employed for the heat management of envelopments, such as buildings and vehicles. However, they deplete a considerable amount of energy. [5][6][7][8] Approximately 44% of the total energy expenditure in buildings can be attributed to heating, cooling, ventilation, and lighting systems in recently constructed buildings. [9] Air conditioners are responsible for the decrease in the driving range of electric vehicles of up to 53.7%. [10,11] It has become a long-term goal for advanced proactive temperature-managed envelopments to maintain an optimal interior air temperature with the least energy expenditure.Solar irradiation is a significant factor influencing energy depletion in the refrigeration systems of vehicles and buildings, accounting for almost 40%-70% of the entire cooling power burden in vehicles and buildings. [12,13] Generally, the solar irradiance power density under AM1.5 can reach 1000 W m −2 , with visible, infrared, and UV percentages of 50%, 43%, and 7%, respectively. [14] To eliminate the negative effects of solar radiation on the cooling energy load of buildings, zero-energy passive radiative cooling is a practical energy conservation tactic. [15][16][17][18][19] Excessive building temperatures in hot weather can be decreased by reflecting the entire solar irradiation while radiating heat to frigid cosmic space. [19][20][21][22][23][24] In the past few years, extensive efforts have been made to promote daytime radiative cooling technology. Numerous materials and structures have been proposed to improve the cooling performance using multilayer films, [25,26] photonic crystals, [27] dielectric particle mixtures, [28][29][30][31][32] micro/nanoporous structures, [33][34][35] and biomimetic wrinkle structures. [36,37] Nevertheless, most daytime radiative cooling technologies do not consider lighting and esthetic purposes and cannot be applied to objects such as the windows and glass curtain walls of buildings and vehicles. [38][39][40][41][42] Conventional windows (particularly skylights) in vehicles and buildings transmit almost 90% of the total incident solar radiation [43][44][45] Common glass without spectral regulation effect cannot offer an energy-saving function, and radiative cooling technology without visible transparency cannot satisfy the illumination and esthetic demands. Herein, the concept of utilizing a biomimetic beetle cuticle structure, guided by principles of Chinese Taoist philosophy, is proposed to accomplish efficient radiative regulation. Subsequently, low-cost biomimetic radiative cooling (Bio-RC) glass is presented, which can reduce the temperature of buildings throughout daytime by blocking near-infrared (NIR) radiation, conveying visible light, and emitting heat within the atmospheric window. Utilizing only three laye...