We present results of Raman scattering experiments on tetragonal (Y1−yCay)Ba2Cu3O6+x for doping levels p(x, y) between 0 and 0.07 holes/CuO2. Below the onset of superconductivity at psc1 ≈ 0.06, we find evidence of a diagonal superstructure. At psc1, lattice and electron dynamics change discontinuously with the charge and spin properties being renormalized at all energy scales. The results indicate that charge ordering is intimately related to the transition at psc1 and that the maximal transition temperature to superconductivity at optimal doping T max c depends on the type of ordering at p > psc1. 74.20.Mn, In cuprates the maximal transition temperature to superconductivity T max c depends on the compound class. In contrast, the variation of T c with doping p does not, and superconductivity exists between approximately 0.05 and 0.27 holes per CuO 2 formula unit in clean samples [1]. In the presence of disorder this range shrinks [1] leading to a sample-specific onset point of superconductivity at p sc1 ≥ 0.05. In addition to superconductivity, short-range antiferromagnetism with the domains separated by quasi one-dimensional charged stripes can occur [2,3,4,5,6]. In La 2−x Sr x CuO 4 (p = x), this superstructure is oriented along the diagonals of the CuO 2 plane below p sc1 and rotates by 45• at p sc1 [7]. This rotation was also seen in the low-energy electronic Raman spectra where the ordering-related response flips symmetry [8].For p > p sc1 superstructures are observed in all cuprates [3,6,9,10,11,12]. However, the type of ordering and its relationship to superconductivity is rather complicated to pin down [5,13,14]. In a few compounds the lattice stabilizes static spin and charge superstructures and the superconducting transition temperature is reduced or quenched [3,6]. In most of the cases fluctuating order prevails, and it is particularly hard to detect the charge part [5,13]. Raman spectroscopy was found to be a viable method [8].Inelastic (Raman) scattering of light is capable of probing most of the excitations in a solid including lattice vibrations, spins, and electrons, as well as their interactions [15]. Since the polarizations of the incident and the scattered photons can be adjusted independently, many of the excitations can be sorted out via the selection rules. For instance, the transport properties of conduction electrons can be measured independently in different regions of the Brillouin zone [15,16], and the orientation of (fluctuating) charged stripes can be determined [8]. A detailed model calculation [17] demonstrated that in addition to the symmetry selection rules the dependence on energy and temperature of the response related to stripes can be understood quantitatively (Fig. 1) in terms of charge-ordering fluctuations.In this paper, we focus on the "high-T c " compound YBa 2 Cu 3 O 6+x (Y-123) at doping levels 0 ≤ p ≤ 0.07. The purpose is to gain insight into the nature of the onset of superconductivity at p sc1 ≈ 0.06 and into possible discrimination criteria to the "low-T c " comp...