The gradual increase in the amount
of fines (<20 μm) deposited in a hydrotreating reactor results
in a sudden pressure drop, leading to premature reactor shutdown.
In addition to the nature of the fine particles, it is believed that
the particle deposition is a function of the process parameters of
the reactor. Among the process conditions that influence the hydrotreating
process, temperature and pressure have been identified as key variables;
therefore their impact on fines deposition on NiMo/γAl2O3 catalyst was studied. Model fine particles were suspended
in light gas oil (LGO) feed, and the feed was hydrotreated in a batch
reactor. The catalyst was characterized to understand its interaction
with the model fine particles. Mass balance results and SEM images
were used to quantitatively analyze the deposition of fine particles
on the catalyst bed. The statistical analyses were performed using
central composite design (CCD) to optimize the hydrotreating conditions
for bed deposition and sulfur conversion as a function of process
parameters such as temperature (355–375 °C), pressure
(1200–1400 psig), and particle loading (1–1.5 g of fines)
in 200 mL of oil. High fines concentration in the feed (particle loading)
and high temperature led to higher bed deposition. The results obtained
helped in understanding the impact of process parameters on particle
deposition in a batch reactor and not in a packed bed reactor. The
optimum temperature to have a significant sulfur conversion with least
fines deposition for LGO feed with process conditions within the boundary
of this research for a batch reactor was found to be in range of 360
to 364 °C.