In this paper, we try to discuss the mechanism of synchronization or cluster synchronization in the coupled Van der Pol oscillator networks with different topology types by using the theory of rotating periodic solutions. The synchronous solutions here are transformed into rotating periodic solutions of some dynamical systems. By analyzing the bifurcation of rotating periodic solutions, the critical conditions of synchronous solutions are given in three different networks. We use the rotating periodic matrix in the rotating periodic theory to judge various types of synchronization phenomena, such as complete synchronization, anti-phase synchronization, periodic synchronization, or cluster synchronization. All rotating periodic matrices which satisfy the exchange invariance of multiple oscillators form special groups in these networks. By using the conjugate classes of these groups, we obtain various possible synchronization solutions in the three networks. In particular, we find symmetry has different effects on synchronization in different networks. The network with better symmetry has more elements in the corresponding group, which may have more types of synchronous solutions. However, different types of symmetry may get the same type of synchronous solutions or different types of synchronous solutions, depending on whether their corresponding rotating periodic matrices are similar.