Please cite this article as: Gamazo, P., Saaltink, M.W., Carrera, J., Slooten, L., Bea, S.A., Gran, M., Modeling the influence of MgSO 4 invariant points on multiphase reactive transport process during saline soil evaporation, Physics and Chemistry of the Earth (2013), doi: http://dx.doi.org/10.1016/j.pce. 2013.02.001 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.
Modeling the influence of MgSO
Abstract:In the present work, we modeled a laboratory experiment where a sand column saturated with a MgSO 4 solution is subject to evaporation. We used a compositional formulation capable of representing the effect of geochemistry on flow and transport for concentrated solutions under extreme dry conditions. The model accounts for the water sink/sources terms due to hydrated mineral dissolution/precipitation and the occurrence of invariant points, which prescribe the water activity. Results show that the occurrence of the invariant points at the top of the domain could affect the vapor flux at the column top and salt precipitation along the column. In fact, the invariant points occurrence could explain the spatial fluctuation on the salt precipitates formation. Results also suggest that the complex hydrochemical interactions occurring during soil salinization, including osmotic effects, are crucial not only to understand the salt precipitation, but also the evaporation rate.
Keywords:• soil evaporation• coupling effects• multiphase reactive transport
Highlights:• Modeling evaporation of sand column with MgSO 4 solution.• Model involves oven dry conditions, high salinity, hydrated mineral precipitation.• Coupling effects: geochemical reactions on water content and therefore on flow.• Modeling invariant points: mineral paragenesis prescribes water activity.