In the last two decades, a vast variety of topological phases have been described, predicted, classified, proposed, and measured. While there is a certain unity in method and philosophy, the phenomenology differs wildly. This work deals with the simplest such case: fermions in one spatial dimension, in the presence of a symmetry group G, which contains anti-unitary symmetries. A complete classification of topological phases, in this case, is available. Nevertheless, these methods are to some extent lacking as they generally do not allow to determine the class of a given system easily. This paper will take up proposals for non-local order parameters defined through anti-unitary symmetries. They are shown to be homotopy invariants on a suitable set of ground states. For matrix product states, an interpretation of these invariants is provided: in particular, for a particle–hole symmetry, the invariant determines a real division super algebra [Formula: see text] such that the bond algebra is a matrix algebra over [Formula: see text].