Self-healing
materials inspire the next generation of multifunctional
wearables and Internet of Things appliances. They expand the realm
of thin film fabrication, enabling seamless conformational coverage
irrespective of the shape complexity and surface geometry for electronic
skins, smart textiles, soft robotics, and energy storage devices.
Within this context, the layer-by-layer (LbL) technique is versatile
for homogeneously dispersing materials onto various matrices. Moreover,
it provides molecular level thickness control and coverage on practically
any surface, with poly(ethylenimine) (PEI) and poly(acrylic acid)
(PAA) being the most used materials primarily employed in self-healing
LbL structures operating at room temperature. However, achieving thin
film composites displaying controlled conductivity and healing ability
is still challenging under ambient conditions. Here, PEI and PAA are
mixed with conductive fillers (gold nanorods, poly(3,4-ethylene dioxythiophene):
polystyrenesulfonate (PEDOT:PSS), reduced graphene oxides, and multiwalled
carbon nanotubes) in distinct LbL film architectures. Electrical (AC
and DC), optical (Raman spectroscopy), and mechanical (nanoindentation)
measurements are used for characterizing composite structures and
properties. A delicate balance among electrical, mechanical, and structural
characteristics must be accomplished for a controlled design of conductive
self-healing composites. As a proof-of-concept, four LbL composites
were chosen as sensing units in the first reported self-healing e-tongue.
The sensor can easily distinguish basic tastes at low molar concentrations
and differentiate trace levels of glucose in artificial sweat. The
formed nanostructures enable smart coverages that have unique features
for solving current technological challenges.