Abstract. Corundum- and spinel-bearing symplectites after muscovite were found in
ultrahigh-pressure (UHP) eclogites from the Dabie terrane, China. Three
types of symplectites were recognized based on their mineral assemblages:
(1) symplectitic intergrowths of corundum + plagioclase + biotite after
phengite (CPB), (2) symplectitic intergrowths of spinel + plagioclase +
biotite after phengite (SPB), and (3) symplectitic intergrowths of spinel
+ plagioclase after paragonite (SP). The microtextures and mineral
assemblages of the symplectites, in combination with the results of
thermodynamic modeling on local regions, indicate that these symplectites
formed by the breakdown of phengite and paragonite during the granulite-facies metamorphic overprint (770–850 ∘C) of the eclogite at pressures
of 0.8–0.9 GPa. Dehydration partial melting reactions occurred during the
breakdown of muscovite, which leads to the formation of thin plagioclase
films (silicate melts) along grain (garnet, rutile, quartz) boundaries. Mass
balance calculations indicate that the development of CPB and SPB
symplectites after phengite requires the introduction of Al, Ca, Na, and Fe
and loss of Si, Mg, and K. However, the formation of SP symplectites after
paragonite requires the input of Mg, Ca, and Fe and removal of Si, Al, and
Na. By summarizing the occurrence and growth mechanism of
corundum- and spinel-bearing symplectites in global UHP terranes, we find that
such symplectites can form by both the subsolidus replacement of an Al-rich
anhydrous mineral (kyanite) and the dehydration melting of an Al-rich
hydrous phase during high-temperature metamorphism. This study reveals that
muscovite-bearing eclogites may experience multiple episodes of partial
melting during the slab exhumation, not only at the high-pressure (HP)
exhumation stage but also at the lower-pressure metamorphic overprinting stage.
Kyanite is a reaction product during the HP partial melting, whereas the
low-pressure (LP) melting will consume kyanite. We propose that the
occurrence of corundum- and spinel-bearing symplectites after muscovite in
eclogites is a potential mineralogical indicator of LP melting in exhumed
slabs.