One of the advantages of microplasmas is that it can be generated using any phase of materials, namely, gases, liquids, and solids. We developed methods to generate microplasmas by pulsed discharge utilizing ethanol filaments grown from the tip of a Taylor cone, which were created by the electrostatic force between electrodes in air. The structures of the filament and Taylor cone were affected by electrode separation, applied voltage, electrode shape, and the mass of liquid. Vaporization and dissociation of ethanol were confirmed in the pulsed discharge of the liquid filament, because the atomic line of hydrogen was observed in optical emission spectroscopy.