Easy-to-Make Polymer Hydrogels by UV-Curing for the Cleaning of Acrylic Emulsion Paint Films

Abstract

The cleaning of acrylic emulsion paint surfaces poses a great challenge in the conservation field, due to their high water sensitivity. In this article, we present easy-to-make polymer hydrogels, made by UV-photopolymerization, that show excellent cleaning properties. The formulation of hydrogels obtained by UV-curing and their performance as dry cleaners for acrylic paints was investigated. First, different hydrogel formulations based on functional acrylic monomers were used to formulate a series of UV cross-linked hydrogels by fast UV photopolymerization. Their effectiveness on surface dirt removal was investigated by SEM microscopy and colorimetry. The hydrogels showed excellent cleaning properties and controlled water release, and they still performed satisfactorily after several cleaning uses. The obtained UV-hydrogels were compared to the well-known agar gels, showing benefits in terms of reducing excess water. This article shows that easy-to-make UV-cured hydrogels are an efficient tool for the cleaning of surface dirt from water-sensitive paintings, overcoming the limits of traditional cleaning methods.

A Brief Overview of Polymers Science and Technology, in Spain

“…Sebastián Muñoz-Guerra and Antxon Martínez de Ilarduya Enzymatic synthesis of poly(butylene succinate-co-caprolactone) copolyesters [45] Irene Cárdaba Irene Cárdaba, David Mecerreyes UV-photopolymerization to easily make polymer hydrogels with cleaning properties [46] Alba Martínez Carlos Sánchez-Somolinos Photolithographic technique to prepare surface relief polymer structures [47] Fundamental aspects of polymers science…”