2023
DOI: 10.1016/j.chemosphere.2022.137690
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Ecotoxicological characteristics and properties of zinc-modified biochar produced by different methods

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Cited by 6 publications
(8 citation statements)
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“…Wet impregnation modification facilitated the introduction of higher concentrations of metals, leading to the formation of metal oxides on the biochar surface and an improvement in the porous structure. Interestingly, this comparative study of the ecotoxicological characteristics of Zn-decorated biochar prepared by either pretreatment of the biomass or post-treatment of the biochar demonstrated that the final biochar Zn was found to be distinctly different [51]. For example, post-treatment led to biochar Zn with a higher content of polyaromatic hydrocarbons and thus more toxicity.…”
Section: Sequence Of Wetness Impregnation/pyrolysismentioning
confidence: 88%
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“…Wet impregnation modification facilitated the introduction of higher concentrations of metals, leading to the formation of metal oxides on the biochar surface and an improvement in the porous structure. Interestingly, this comparative study of the ecotoxicological characteristics of Zn-decorated biochar prepared by either pretreatment of the biomass or post-treatment of the biochar demonstrated that the final biochar Zn was found to be distinctly different [51]. For example, post-treatment led to biochar Zn with a higher content of polyaromatic hydrocarbons and thus more toxicity.…”
Section: Sequence Of Wetness Impregnation/pyrolysismentioning
confidence: 88%
“…The order of wet impregnation and pyrolysis significantly influences the physicochemical properties of the biochar composites, such as the pore structure and the specific surface area. SEM analysis indicated that pre-treatment followed by pyrolysis induces the catalyzed carbonization of the biomass and the formation of pores and leads to a considerable surface area [51]. This contrasts with the post-treatment of the pyrolyzed samples, containing less unevenly distributed inorganic particles/larger crystal clusters and resulting in the blocking of pores and reductions in the specific surface area (Figure 4).…”
Section: Sequence Of Wetness Impregnation/pyrolysismentioning
confidence: 99%
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“…Modified BC may potentially have negative effects on microorganisms in salt-affected soils. In the research of Marcinczyk et al (2023), the porosity of BC decreased, while the content of Zn and Cu increased, and it contained a greater concentration of dissolved organic carbon (DOC). Owing to these changes, the modified BC demonstrated an increased toxicity towards A. fischeri and D. manga.…”
Section: Soil Microorganisms and Soil Enzymesmentioning
confidence: 99%
“…For instance, Zn may adversely affect soil microorganisms. Marcinczyk et al (2023) discovered that BC modified with Zn after pyrolysis at 700°C had toxic effects on A. fischeri, reducing its luminescence by 50%. Modified BC may also aggravate the risk of soil salinization and Na + stress on plants.…”
Section: Metal Salt Modificationmentioning
confidence: 99%