Polyacrylamide
hydrogel used in conformance control is subjected
to poor stability at an elevated temperature. In this paper, nanosilica
has been found to be a very effective stabilizing agent for the polyacrylamide/polyethylenimine
hydrogel, and the reinforcing performance of nanosilica on the hydrogel
was investigated in detail. The result showed that the strength of
hydrogel is enhanced obviously by the nanosilica, and the hydrogel
syneresis is also significantly inhibited by the nanosilica, which
can increase the hydrogel stability time from 18 to 180 days at 130
°C. Besides, nanosilica can increase the shear viscosity and
hydrodynamic radius of polyacrylamide, and the bound water in the
hydrogel is also grown in the presence of nanosilica. In comparison
to the micromorphology of common hydrogel, the dense and strong mesh
structure is formed as a result of the reinforcing behavior of nanosilica.
According to the above results, it is inferred that the silanol group
of nanosilica cross-links with the amidogen of polyacrylamide via
the hydrogen bond, which is considered as the primary cause of the
reinforcing performance of nanosilica for the hydrogel. In addition,
as a result of the improving strength and stability and increasing
absorption of the polymer to rock surface, the hydrogel enhanced by
nanosilica has a higher water shutoff ratio and residual resistance
factor and a longer period of validity.