In the article research results are presented, the aim of which is to provide high quality and reliability while using heat-protective structures for machines and people. Textile materials perform important function contacting moisture in the atmosphere. Results of moist environment textile structure and properties research are also presented here. It was established that multilayer structure with free elementary cells, including knitwear, for the purposes of barrier maintenance of moisture level is not sufficient. Based on the performed experimental research, new characteristics and properties pattern defining behavior of materials while contacting liquids (wetting, capillarity, moisture, hygroscopy) are established. Recommendations relating to groups and samples of textile materials are given. The research was made in Don State Technical University within the framework of State Assignment of the Ministry of education and science of Russia under the project 11.9194.2017/BCh.