Biogas produced through anaerobic degradation of waste activated sludge (WAS) in wastewater treatment plants has gained much more attention as it is a renewable energy resource. An apparent advantage of anaerobic digestion is the generation of biogas that presents a renewable substitute for utilization of fossil fuels. It was observed that pretreatment has to be done prior to anaerobic degradation (AD) to enhance the biogas generation. This review deals with various pretreatments-chemical, physical, mechanical, combinative, phase-separated pretreatment, their mode of action, advantages and their impact on biogas generation. An extensive review of these pretreatment techniques could plausibly aid in increasing the biogas production and thus rises the sustainable energy generation.