Effect of alloy formation in Ag−Au system on electrical double layer structure and hydrogen evolution kinetics

Bobrinskaya, E. V.; Morozova, N. B.; Vvedenskii, A. V.

doi:10.1007/bf02758393

Cited by 2 publications

(2 citation statements)

References 8 publications

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“…It can be seen that the Tafel slopes have no obvious changes. In general, HER mechanisms in the acid solution include the Volmer–Tafel mechanism (Equations (A) and (B) in the Supporting Information) and the Volmer–Heyrovsky mechanism (Equations (A) and (C) in the Supporting Information) . The resulting Tafel slope values under different back‐gate voltages indicate that the Volmer–Heyrovsky mechanism controls the reaction.…”

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Superior Hydrogen Evolution Reaction Performance in 2H‐MoS₂ to that of 1T Phase

Zhang

Liao

Pan

et al. 2019

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Water splitting using electricity generated by wind or solar power has been proposed as an effective strategy for sustainable hydrogen production. [1][2][3] Among the family of hydrogen In the hydrogen evolution reaction (HER), energy-level matching is a prerequisite for excellent electrocatalytic activity. Conventional strategies such as chemical doping and the incorporation of defects underscore the complicated process of controlling the doping species and the defect concentration, which obstructs the understanding of the function of band structure in HER catalysis. Accordingly, 2H-MoS 2 and 1T-MoS 2 are used to create electrocatalytic nanodevices to address the function of band structure in HER catalysis. Interestingly, it is found that the 2H-MoS 2 with modulated Fermi level under the application of a vertical electric field exhibits excellent electrocatalytic activity (as evidenced by an overpotential of 74 mV at 10 mA cm −2 and a Tafel slope of 99 mV per decade), which is superior to 1T-MoS 2 . This unexpected excellent HER performance is ascribed to the fact that electrons are injected into the conduction band under the condition of back-gate voltage, which leads to the increased Fermi level of 2H-MoS 2 and a shorter Debye screen length. Hence, the required energy to drive electrons from the electrocatalyst surface to reactant will decrease, which activates the 2H-MoS 2 thermodynamically.

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Superior Hydrogen Evolution Reaction Performance in 2H‐MoS₂ to that of 1T Phase

Zhang

Liao

Pan

et al. 2019

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“…The upper peak value of the first one million loads was 61.0 kN and the lower peak value was 25.0 kN; the upper peak of the last 1 million loads was 90.0 kN and the lower peak was 36.0 kN. The actual load spectrum is shown in Figures 4, and 5 [39, 40]. During the first one million tests, no visible cracks appeared on the surface of the fireproof coating of the test piece.…”

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confidence: 99%

Anti‐cracking performance test of thick steel structure fireproof coating under vibration fatigue load for critical health infrastructure

Zhang

Liu

et al. 2022

The Journal of Engineering

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The infrastructure of health and biomedical facilities caters to a variety of purposes that frequently vary over time, flexibility and adaptability are crucial traits for future re‐configuration. This paper chooses the relevant cement‐based solid metal structures fire‐retardant coatings available on the market as the test object and performs high‐cycle fatigue stress experiments on steel structural elements painted with cement‐based thick steel structure fire‐retardant varnishes. It simulates the deformation of the steel structure under the daily variable load of high‐rise steel structure buildings, investigates the cracking and adhesion properties of the fireproof coating on the surface of the steel component under the repeated action of this load, and evaluates the service life of the fireproof coating for the steel structure under normal use conditions. When the best dosage of modified epoxy resin E51 is 10%, the best ratio of emulsifier is m(SDS): m(OP‐10 = 2:1, the best dosage is 1.25% of the monomer quality, and the best dosage of G04 is 3% of the monomer mass, and the particle size distribution of the latex particles is concentrated. The average particle size of the emulsion is 138.3 nm, and the hardness and water resistance of the paint film are the best.

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Effect of alloy formation in Ag−Au system on electrical double layer structure and hydrogen evolution kinetics

Cited by 2 publications

References 8 publications

Superior Hydrogen Evolution Reaction Performance in 2H‐MoS₂ to that of 1T Phase

Superior Hydrogen Evolution Reaction Performance in 2H‐MoS₂ to that of 1T Phase

Anti‐cracking performance test of thick steel structure fireproof coating under vibration fatigue load for critical health infrastructure

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Effect of alloy formation in Ag−Au system on electrical double layer structure and hydrogen evolution kinetics

Cited by 2 publications

References 8 publications

Superior Hydrogen Evolution Reaction Performance in 2H‐MoS2 to that of 1T Phase

Superior Hydrogen Evolution Reaction Performance in 2H‐MoS2 to that of 1T Phase

Anti‐cracking performance test of thick steel structure fireproof coating under vibration fatigue load for critical health infrastructure

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Product

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Superior Hydrogen Evolution Reaction Performance in 2H‐MoS₂ to that of 1T Phase

Superior Hydrogen Evolution Reaction Performance in 2H‐MoS₂ to that of 1T Phase