Gels are soft functional materials
with solid networks and open
pores filled with solvents (for wet gels) or air (for aerogels), displaying
broad applications in tissue engineering, catalysis, environmental
remediation, energy storage, etc. However, currently
known gels feature only a single (either solid–liquid or solid–vapor)
interface, largely limiting their application territories. Therefore,
it is both fundamentally intriguing and practically significant to
develop conceptually new gel materials that possess solid–liquid–vapor
multiple interfaces. Herein, we demonstrate a unique solid–liquid–vapor
triphase gel, named as aerohydrogel, by gelling of a poly(vinyl alcohol)
aqueous solution with glutaraldehyde in the presence of superhydrophobic
silica aerogel microparticles. Owing to its continuous solid, liquid,
and vapor phases, the resultant aerohydrogel simultaneously displays
solid–liquid, solid–vapor, and liquid–vapor interfaces,
leading to excellent properties including tunable density (down to
0.43 g·cm–3), considerable hydrophobicity,
and excellent elasticity (compressive ratio of up to 80%). As a proof-of-concept
application, the aerohydrogel exhibits a higher evaporative cooling
efficiency than its hydrogel counterpart and a better cooling capability
than the commercial phase change cooling film, respectively, showing
promising performance in cooling various devices. Moreover, the resulting
aerohydrogel could be facilely tailored with specific (e.g., magnetic) properties for emerging applications such as solar steam
generation. This work extends biphase gel (hydrogel or aerogel) to
solid–liquid–vapor triphase gel, as well as provides
a promising strategy for designing more aerohydrogels serving as soft
functional materials for applications in various emerging fields.